ZSM-5 ụdị zeolite, nke elu-silica zeolite na-enwe a Si / Al ruru nke ruo 1000 na n'elu, na-egosi hydrophobic e ji mara. Ọdịdị atụmatụ nke ndị dị otú ahụ a zeolite bụ na vetikal na kehoraizin akụkụ bụ crystalline alum inosilicate esịnede 10-membered ọwa. Ihe owuwu na-emi esịnede asatọ 5-membered yiri mgbaaka, nke nwere ọwa na na na-enweghị onu-free cavities. ZSM-5 nwere ihe abụọ tent nke cross ọwa, otu onye nke bụ ellipse, na window n'obosara-ya bụ 0,55 ka 0.60nm. Dị ka mmeghachi omume ohere bụ yiri udi nke ohere, ndị zeolite nwere a udi nhọrọ mmetụta na reactants na ngwaahịa. Ọzọkwa, ZSM-5 bụ ezigbo akụrụngwa nke nhọrọ mkpali n'ihi na adabako Ọdịdị na hydrothermal kwụsie ike.
ZSM-5 ụdị zeolite na-ebe etinyere Petrochemical nhazi ọrụ, etinyere na fluidifying, catalyzing na cracking usoro dị ka otu nnyemaaka maka amị ọzọ propylene na gasị gas, na rụọ ọrụ ndị octane nọmba nke mmanụ ụgbọala. Ke adianade do, zeolite nwere ike etinyere na mmepụta nke ethylbenzene, xylene, phenol, pyridine, wdg
Ngwa:
1.ZSM - 5 molekụla myọ eji maka FCC mkpali: ot SiO2 / Al2O3 ruru bụ n'agbata 40 ruo 50.
2.ZSM - 5 molekụla myọ eji maka FCC mmanụ ụgbọala nwekwara iji belata olefin: ot SiO2 / Al2O3 ruru bụ n'agbata 38 ka 40.
3.ZSM - 5 molekụla myọ eji maka resid catalytic cracking: ot SiO2 / Al2O3 ruru bụ n'etiti 25 na 30.
4.ZSM - 5 molekụla sieves na chemical ụlọ ọrụ, ezi chemical ụlọ ọrụ na ọtụtụ-eji udi-nhọrọ catalysis, dị ka diethylbenzene mkpali, xylene isomerization mkpali, ethyl acetate, ethylene glycol, ethylene glycol butyl ether nke mkpali nwere a dịgasị iche iche nke ojiji.
Technic ụbọchị:
item |
unit |
min |
ahụkarị |
Max |
gbasara nyocha Method |
ikwu crystallinity |
% |
90 |
93 |
X-ray diffractometer |
|
Total kpọmkwem n'elu |
m 2/ g |
320 |
360 |
Adsorption |
|
Microporous kpọmkwem n'elu |
m 2/ g |
270 |
280 |
Adsorption |
|
Silica-alumina ruru |
/ |
25 |
27,5 |
30 |
XRP |
Na 2O |
wt% |
0,04 |
0.1 |
Ire ọkụ Photometric Analysis |
|
NKE 42 |
wt% |
0,20 |
0.4 |
XRP |
|
Cl- |
ppm |
70 |
Chemical Analysis |
||
LOI |
wt% |
10 |
Gravimetric Analysis |
||
D, 50 |
μm |
6 |
9 |
Lase Gbasaanụ Nkesa |
|
D, 90 |
μm |
9.0 |
15 |
Laser Gbasaanụ Nkesa |
|
> 100μm |
0 |
0,06 |
Laser Gbasaanụ Nkesa |